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E-Beam Resists: Investigating Chemically Amplified and Non-chemically Amplified Systems

Introduction

The semiconductor industry currently uses photolithographic techniques for production of semiconductor devices.  Over the years there has been a steady reduction in the wavelength of the light used to print these devices since wavelength reduction increases the resolution.  Today both immersion lithography at 193 nm and extreme ultraviolet at 10-20 nm are being pursued in research and development.  Both of these systems rely on resists with chemical amplification.

Background

The chemically amplified resist systems consist of a photo-acid generator (PAG) and a polymer that incorporates an acid-sensitive functional group, which serves as a solubility switch.  The sensitivity of the chemically amplified system is advantageous, but the sensitivity comes with a loss in resolution that is caused by the PAG.
Once the acid is generated, it diffuses into areas of the resist which were not exposed to light.  The post exposure bake further propagates this problem.  The developed features on the device therefore end up wider than originally intended (bias), and they are not smooth (line-edge roughness, LER).  Both the bias and LER put limitations on the size of the features that can be produced by this technique.
A chemically amplified or gain mechanism is required to provide high productivity for the expensive production tools, but this is currently achieved at the expense of the blur of the features (bias and LER).  We propose a method to decouple the gain from the blur. 
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Original page created 02/22/06